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- W2100031353 abstract "Abstract Two new and efficient dual catalytic procedures for the synthesis of tri‐ and tetrasubstituted alkenes using aryl bromides and chlorides are reported. The formation of these vinyl arenes occurs independently in a one‐pot relay and a one‐pot cooperative procedure using well‐defined Pd and Cu N ‐heterocyclic carbene (NHC) complexes. Mechanistic studies were performed to elucidate the key role of the solvent in each procedure as well as the formation of the key intermediate, [Cu(alkenylboron)(NHC)], which allows transmetalation with the Pd‐NHC co‐catalyst in the cooperative catalysis." @default.
- W2100031353 created "2016-06-24" @default.
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- W2100031353 date "2015-06-26" @default.
- W2100031353 modified "2023-10-07" @default.
- W2100031353 title "Versatile Relay and Cooperative Palladium(0)<i>N</i>-Heterocyclic Carbene/Copper(I)<i>N</i>-Heterocyclic Carbene Catalysis for the Synthesis of Tri- and Tetrasubstituted Alkenes" @default.
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- W2100031353 doi "https://doi.org/10.1002/cctc.201500268" @default.
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