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- W2100033221 abstract "A general and one-step method was developed as a versatile route to fabricate ‘smart’ self-assemblies via γ-irradiation of simple cyclic ethers under air atmosphere. Only by one-step irradiation in water, a series of amphiphilic oligomers containing oligo(ethylene glycol) (oligo-EG) side chains and their supramolecular assemblies with plentiful morphologies could be prepared, including flower-shaped aggregates, microsphere aggregates, well-defined core–shell micelles and nano-sized capsules. The morphology of the supramolecular assemblies could be facilely adjusted based on the different structures of the cyclic ethers. Moreover, the core–shell micelles prepared by irradiating dicyclohexano-18-crown-6 (DCH18C6) aqueous solutions could be easily controlled by simple external stimulations, such as varying temperature, pH and adding metal ions. Based on the results of a series of cyclic ethers, it is expected that this work can provide a novel and general approach to design and construct ‘smart’ supramolecular assemblies for biomedical and industrial applications." @default.
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- W2100033221 date "2013-01-01" @default.
- W2100033221 modified "2023-09-22" @default.
- W2100033221 title "One-step radiation-induced construction of multi-responsive self-assemblies using simple cyclic ethers" @default.
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- W2100033221 doi "https://doi.org/10.1039/c3sm50327e" @default.
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