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• W2100039825 abstract "Sea the synthesis: At ambient temperature, tert-butyllithium promotes a Barbier-type macrocyclization in the first total synthesis of (−)-gymnodimine (Ts: toluene-4-sulfonyl; TBS: tert-butyldimethylsilyl), a member of the spirocyclic-imine family of marine toxins. The synthesis also features a vinylogous Mukaiyama aldol process to couple the labile butenolide moiety onto a macrocyclic ketone intermediate." @default.
• W2100039825 created "2016-06-24" @default.
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• W2100039825 date "2009-09-17" @default.
• W2100039825 modified "2023-10-09" @default.
• W2100039825 title "Enantioselective Total Synthesis of the Marine Toxin (−)-Gymnodimine Employing a Barbier-Type Macrocyclization" @default.
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• W2100039825 doi "https://doi.org/10.1002/anie.200903432" @default.
• W2100039825 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4041538" @default.
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• W2100039825 hasPublicationYear "2009" @default.
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