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• W2100040561 startingPage "83" @default.
• W2100040561 abstract "The sequence and structure of lyotropic liquid crystals formed in C12–C16 alkyltrimethylammonium surfactants with hydrolysable and multivalent phosphate (PO43−, HPO42− and H2PO4−), oxalate (HC2O4− and C2O42−), and carbonate (HCO3−/CO32−) counterions were determined using a concentration gradient method coupled with polarising optical microscopy and small angle X-ray scattering. In addition to the discrete cubic (I1, space group Pm3n) and hexagonal (H1, p6m) phases, almost all of these surfactants also formed the (previously) rare hexagonally closest-packed spheres (HCPS, P63/mmc) phase at compositions between the Pm3n cubic and L1 micellar phases. This structure has not been previously observed in cationic surfactants, but is readily achieved by using strongly hydrated counterions to stabilise spherical micelles at high concentrations." @default.
• W2100040561 created "2016-06-24" @default.
• W2100040561 creator A5012639933 @default.
• W2100040561 creator A5047184376 @default.
• W2100040561 date "2014-01-01" @default.
• W2100040561 modified "2023-09-27" @default.
• W2100040561 title "Hexagonal closest-packed spheres liquid crystalline phases stabilised by strongly hydrated counterions" @default.
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• W2100040561 doi "https://doi.org/10.1039/c3sm52339j" @default.
• W2100040561 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/24651949" @default.
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