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- W2100044792 abstract "The use of electron paramagnetic resonance spectroscopy to study the superoxide intermediates, generated by end-on and side-on adsorption of the naturally abundant and 17O-enriched dioxygen on catalytic surfaces is discussed. Basic mechanisms of O2 − radical formation via a cationic redox mechanism, an anionic redox mechanism, and an electroprotic mechanism are illustrated with selected oxide-based systems of catalytic relevance. Representative experimental spectra of various complexities are analyzed and their diagnostic features have been identified and interpreted. The molecular nature of the g and A tensors of the electrostatic and covalent superoxide adducts is discussed in detail within the classic and density functional theory based approaches." @default.
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- W2100044792 date "2015-08-13" @default.
- W2100044792 modified "2023-09-26" @default.
- W2100044792 title "Diagnostic Features of EPR Spectra of Superoxide Intermediates on Catalytic Surfaces and Molecular Interpretation of Their g and A Tensors" @default.
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- W2100044792 doi "https://doi.org/10.1007/s11244-015-0420-y" @default.
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