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- W2100045661 abstract "An efficient new route to the benzo[b]xanthone system has been developed and applied to the synthesis of several new derivatives. The cycloaddition reactions of chromone-3-carboxaldehydes 12, reacting as dienophiles, with ortho-benzoquinodimethane 7 gave a diastereomeric mixture of cycloadducts 8 and 9. The formation of these compounds results from the Diels–Alder reactions of 12 and 7 followed by the in situ deformylation. The oxidation of adducts 8 and 9 with dimethyl sulfoxide in the presence of iodine gave the novel benzo[b]xanthones 11 in good yields." @default.
- W2100045661 created "2016-06-24" @default.
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- W2100045661 date "2002-01-01" @default.
- W2100045661 modified "2023-10-16" @default.
- W2100045661 title "Diels–Alder reactions of chromone-3-carboxaldehydes with ortho-benzoquinodimethane. New synthesis of benzo[b]xanthones" @default.
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- W2100045661 doi "https://doi.org/10.1016/s0040-4020(01)01131-0" @default.
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