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- W2100049908 abstract "In control: A cyclization reaction of an allylic β-imidazolinonyl-β-ketoester 1 is carried out in a MnIII-promoted radical cascade. The reaction pathway (5-exo/6-endo or 5-exo/5-exo) can be directed to construct the central cyclopentyl and cyclohexenyl core skeletons (2 and 3) of two classes of oroidin dimers with regiocontrol. An oxidative rearrangement can also be used to convert 2 into 3. PG=protecting group. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z601208_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2100049908 date "2006-06-16" @default.
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- W2100049908 title "Regiocontrol in MnIII-Mediated Oxidative Heterobicyclizations: Access to the Core Skeletons of Oroidin Dimers" @default.
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- W2100049908 doi "https://doi.org/10.1002/anie.200601208" @default.
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