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• W2100057147 abstract "Disproportionation of benzyl alcohol has been identified as the source of toluene formation in the solvent free oxidation of benzyl alcohol using supported gold palladium catalysts. There is a slight increase in the disproportionation reaction, and hence the toluene selectivity, when this reaction is performed in a continuous mode using a micro-packed bed reactor when compared to the same reaction performed in a conventional glass stirred batch reactor. Oxidation and disproportionation reactions respond slightly differently to the changes in reaction parameters, like oxygen concentration and pressure, when a micro packed bed reactor was used instead of a conventional glass stirred reactor. When MgO supported gold–palladium catalysts were used for this reaction, the toluene selectivity reduced substantially at the cost of conversion." @default.
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• W2100057147 date "2013-03-01" @default.
• W2100057147 modified "2023-10-17" @default.
• W2100057147 title "Selective suppression of disproportionation reaction in solvent-less benzyl alcohol oxidation catalysed by supported Au–Pd nanoparticles" @default.
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• W2100057147 doi "https://doi.org/10.1016/j.cattod.2012.05.023" @default.
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