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- W2100060468 abstract "In a microfluidic H-cell, a multi-component self-assembled system is brought out-of-equilibrium by changing the bimodal composition of porphyrin stacks and pyridine-capped dimers. Driven by their different diffusivities, diffusion-controlled separation in methylcyclohexane reveals different compositions when detected in-line and off-line, which demonstrates the kinetic behaviour of this metastable system. The microfluidic technique also proves to be highly equipped to determine diffusion constants of the different assemblies." @default.
- W2100060468 created "2016-06-24" @default.
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- W2100060468 date "2013-01-01" @default.
- W2100060468 modified "2023-09-25" @default.
- W2100060468 title "Controlled perturbation of the thermodynamic equilibrium by microfluidic separation of porphyrin-based aggregates in a multi-component self-assembling system" @default.
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- W2100060468 doi "https://doi.org/10.1039/c2cc36887k" @default.
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