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- W2100061232 abstract "A gold-catalyzed cycloisomerization of 1,6-diynes containing an ynamide propargyl ester or carbonate moiety has been developed that provides an attractive route to a diverse-substituted 3-acyloxy-1,4-dihydrocyclopenta[b]indoles. Mechanistic studies indicate that the reaction likely proceeds through a competitive 1,2-OAc migration followed by [3+2] cycloaddition of the vinyl gold-carbenoid intermediate with the pendant triple bond. The synthetic utility of the obtained cyclopenta[b]indole products was demonstrated by their efficient transformations by deprotection or double-bond isomerization reactions." @default.
- W2100061232 created "2016-06-24" @default.
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- W2100061232 creator A5065482772 @default.
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- W2100061232 date "2014-12-02" @default.
- W2100061232 modified "2023-10-15" @default.
- W2100061232 title "Gold(I)-Catalyzed 1,2-Acyloxy Migration/[3+2] Cycloaddition of 1,6-Diynes with an Ynamide Propargyl Ester Moiety: Highly Efficient Synthesis of Functionalized Cyclopenta[<i>b</i>]indoles" @default.
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- W2100061232 doi "https://doi.org/10.1002/chem.201405965" @default.
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