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- W2100067042 abstract "The addition of Grignard reagents to D-erythro-4-pentenose N-benzyl nitrone 5, which is easily accessible from D-ribose, furnishes ω-unsaturated hydroxylamines that readily undergo Cope−House cyclization to afford pyrrolidine N-oxides. The stereoselectivity of the addition step is altered by either employing organolithium compounds or Lewis acids as complexing agents. The pyrrolidine N-oxides obtained by this sequence serve as key intermediates in the synthesis of 2,5-disubstituted pyrrolidine-3,4-diols (to be discussed in detail separately), both constituting new potential inhibitors of glycosidases." @default.
- W2100067042 created "2016-06-24" @default.
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- W2100067042 date "2001-04-01" @default.
- W2100067042 modified "2023-09-29" @default.
- W2100067042 title "PyrrolidineN-Oxides by Stereoselective Addition of Grignard and Lithium Compounds to 4,5-Dideoxy-2,3-O-isopropylidene-D-erythro-4-pentenoseN-Benzyl Nitrone and Subsequent Cope−House Cyclization" @default.
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- W2100067042 doi "https://doi.org/10.1002/1099-0690(200104)2001:7<1293::aid-ejoc1293>3.0.co;2-4" @default.
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