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- W2100074668 abstract "The use of zinc and aqueous potassium hydroxide for the reductive epoxy ring opening of thebaine (1) and 6-demethoxythebaine (2) is described. The reaction affords exclusively β-dihydrothebaine (3) and 6-demethoxy-β-dihydrothebaine (4), respectively. The synthesis of desoxycodeine-A (9) has been improved and evidence for its configuration is discussed." @default.
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- W2100074668 date "1986-01-01" @default.
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- W2100074668 title "Scission of the epoxy ring in 4,5α-epoxymorphinans: A convenient synthesis of β-dihydrothebaine, 6-demethoxy-β-dihydrothebaine and desoxycodeine-A (Chemistry of opium alkaloids, Part XXI)" @default.
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- W2100074668 doi "https://doi.org/10.1002/recl.19861050104" @default.
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