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- W2100077351 abstract "Abstract Summary: Soluble conjugated random and alternating copolymers (PCz‐PSP) derived from N ‐hexyl‐3,6‐carbazole (Cz) and 1,1‐dimethyl‐2,3,4,5‐tetraphenylsilole (PSP) were synthesized by palladium(0)‐catalyzed Suzuki coupling reactions. The feed ratios of Cz to PSP were 95:5, 90:10, 80:20, 70:30, and 50:50. Chemical structures and optoelectronic properties of the copolymers were characterized by 1 H NMR, 13 C NMR, UV absorption, cyclic voltammetry, photoluminescence, electroluminescence, and field effect transistor. HOMO levels of the copolymers are between −5.15 and −5.34 eV. Single‐layer devices with a configuration of ITO/copolymer/Ba/Al were fabricated and the copolymer with PSP content of 20% displayed the highest external quantum efficiency of 0.77%. Field effect transistors with tantalum pentoxide‐polyacrylonitrile double insulators demonstrated that hole mobilities of the copolymers decreased with their PSP contents, and the hole mobility up to 9.3 × 10 −6 cm 2 · (V · s) −1 could be achieved. Synthesis of coplymers derived from 3,6‐carbazole and silole. magnified image Synthesis of coplymers derived from 3,6‐carbazole and silole." @default.
- W2100077351 created "2016-06-24" @default.
- W2100077351 creator A5038603218 @default.
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- W2100077351 date "2005-10-21" @default.
- W2100077351 modified "2023-10-10" @default.
- W2100077351 title "Conjugated Silole and Carbazole Copolymers: Synthesis, Characterization, Single-Layer Light-Emitting Diode, and Field Effect Carrier Mobility" @default.
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- W2100077351 doi "https://doi.org/10.1002/macp.200500281" @default.
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