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- W2100077938 abstract "Abstract In samples of isotactic polypropylene, the influence of the nucleation agent chinacridine permanent red E3B on the crystallization rate and content of α and β modifications and on the rate and mechanism of the β → α transition was investigated using x-ray diffraction, DSC microcalorimetry, and electron microscopy. It was found that, though E3B increases the content of the β phase, it is also a very efficient nucleation agent for the α-phase crystallization. The β → α transition occurring above 140°C could be characterized by a gradual melting and annealing of the β phase, accompanied by a surface crystallization of the α phase on lateral faces of β lamellae by a mechanism similar to cross-branching of α lamellae. Key Words: Isotactic polypropyleneIsothermal crystallizationMorphologyRecrystallizationTransition β → α" @default.
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- W2100077938 date "1991-09-01" @default.
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- W2100077938 title "Transition of β to α phase in isotactic polypropylene" @default.
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- W2100077938 doi "https://doi.org/10.1080/00222349108215449" @default.
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