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• W2100084767 abstract "C−H functionalization of benzyl silyl ethers by means of rhodium-catalyzed insertions of aryldiazoacetates can be achieved in a highly diastereoselective and enantioselective manner by judicious choice of chiral catalyst or auxiliary. The dirhodium tetraprolinates such as Rh2((S)-DOSP)4 have been widely successful as chiral catalysts in the C−H functionalization chemistry of aryldiazoacetates, but give poor enantioselectivity in the reactions of aryldiazoacetates with benzyl silyl ether derivatives. The use of (S)-lactate as a chiral auxiliary resulted in C−H functionalization with moderately high diastereoselectivity (79−88% de) and enantioselectivity (68−85% ee). The best results (91−95% de, 95−98% ee), however, were achieved using Hashimoto's Rh2((S)-PTTL)4 catalyst." @default.
• W2100084767 created "2016-06-24" @default.
• W2100084767 creator A5001082764 @default.
• W2100084767 creator A5083948798 @default.
• W2100084767 creator A5085639706 @default.
• W2100084767 date "2005-11-17" @default.
• W2100084767 modified "2023-10-09" @default.
• W2100084767 title "Asymmetric Intermolecular C−H Functionalization of Benzyl Silyl Ethers Mediated by Chiral Auxiliary-Based Aryldiazoacetates and Chiral Dirhodium Catalysts" @default.
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• W2100084767 doi "https://doi.org/10.1021/jo051747g" @default.
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