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- W2100086734 abstract "Variations of the Williamson ether synthesis were employed to prepare a range of new derivatives of brominated poly(isobutylene-co-isoprene) (BIIR). Unambiguous characterization of the polymeric products was accomplished by spectroscopic comparisons to low-molecular-weight analogues derived from brominated 2,2,4,8,8-pentamethyl-4-nonene, which served as a model for the reactive functionality found within BIIR. The substitution of bromide from BIIR occurred at moderate temperatures with stoichiometric amounts of quaternary ammonium phenoxide to yield O-alkylation products in high yields. Simple mixtures of BIIR, KOH, and aliphatic alcohols generated the desired allylic ethers when heated above 110 °C in the absence of quaternary ammonium salts. Knowledge gained from these small-molecule alkylations was used to prepare graft copolymers from BIIR and poly(ethylene oxide) through the exploitation of the apparent ability of polyethers to activate potassium alkoxides in nucleophilic substitutions. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 983–992, 2006" @default.
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- W2100086734 date "2005-01-01" @default.
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- W2100086734 title "Synthesis and characterization of ether derivatives of brominated poly(isobutylene-co-isoprene)" @default.
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- W2100086734 doi "https://doi.org/10.1002/pola.21221" @default.
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