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- W2100089904 abstract "Thin films of ten glassy polymers are bonded to copper grids and strained in tension to produce crazes, which are then examined in the transmission electron microscope. The average craze fibril extension ratio λ for each polymer is determined from microdensitometer measurements of the mass thickness contrast of the crazes. The extension ratio λ is found to increase approximately linearly with the chain contour length le between entanglements, as determined from melt elasticity measurements of the entanglement molecular weight of these polymers. These results are analyzed by comparing them with λmax, the maximum extension ratio of an entanglement network in which polymer chains neither break nor reptate (i.e., permanent entanglement crosslinks are assumed). The values of λmax are given by le/d where d, the entanglement mesh spacing in the unoriented glass, is computed from d = k(Me)1/2 with k determined either from small-angle neutron scattering results on isolated chains in the glass or from coil size measurements in dilute solutions of a θ solvent. The craze extension ratios fall somewhat below λmax at low λ but increase to well above λmax for polymers with high le. This comparison suggests a significant contribution due to chain breakage (or reptation) in the higher-λ crazes of large-le polymers, which may arise from the higher true stresses in the craze fibrils (which for a given applied stress increase proportionally to λ). The results also imply that a useful way to increase the “brittle” fracture stress and decrease the ductile-to-brittle transition temperature of a glassy polymer is to decrease its entanglement contour length le." @default.
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- W2100089904 date "1982-05-01" @default.
- W2100089904 modified "2023-10-11" @default.
- W2100089904 title "Effect of molecular entanglements on craze microstructure in glassy polymers" @default.
- W2100089904 doi "https://doi.org/10.1002/pol.1982.180200512" @default.
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