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- W2100092822 abstract "The preparation of organic–inorganic polymer hybrids consisting of carbon–carbon and siloxane chains was investigated by radical polymerization of 3-methacryloxypropyltrimethoxysilane (MAS) followed by acid-catalyzed hydrolytic polycondensation. The condensation of poly(3-methacryloxypropyltrimethoxysilane) (S-PMA) of various molecular weights Mn =830–12000 prepared by polyaddition provided transparent and flexible free-standing hybrid gel films. The mechanical properties of these films were highly dependent on the carbon–carbon chain length: with an increase in the carbon–carbon chain length, the elasticity of gel films increased, while the tensile strength and Young's modulus decreased. Hydrolyzability of S-PMA decreased with an increase in the carbon–carbon chain length, resulting in the formation of rubber-like films with flexibility. © 1998 John Wiley & Sons, Ltd." @default.
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- W2100092822 date "1998-10-01" @default.
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- W2100092822 title "Preparation and properties of silicon-containing polymer hybrids from 3-methacryloxypropyltrimethoxysilane" @default.
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- W2100092822 doi "https://doi.org/10.1002/(sici)1099-0739(199810/11)12:10/11<749::aid-aoc782>3.0.co;2-2" @default.
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