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- W2100114562 abstract "The coordination of a bis(methyliminophosphoranyl)pyridine ligand (L) to copper centres was studied. The use of copper(I) bromide precursors gave access to [LCuBr] (2) in which only one iminophosphorane arm is coordinated to the metal, as observed by X-ray crystallography and MAS 31P NMR. Its fluxional behaviour in solution was demonstrated by VT-31P NMR, and investigated by DFT calculations. On the other hand, coordination of L to [Cu(CH3CN)4]PF6 gave a dimer [L2Cu2](PF6)2 (3) in which the two copper centres do not have the same coordination sphere as shown by X-ray crystallography. Addition of a strong ligand such as PEt3 allows the preparation of a cationic monomeric copper complex (4) in which L has a behaviour similar to that observed for 2. Synthesis of copper(II) complexes was also achieved by chemical oxidation of 2, which shows an irreversible oxidation at −0.36 vs. Fc+/Fc, or directly via the coordination of L to CuBr2. In [LCuBr2] (5), L adopts a pincer coordination. Finally, the catalytic behaviour of copper(I) complexes 2 and 3 was investigated in cyclopropanation reactions and [3 + 2] cycloadditions." @default.
- W2100114562 created "2016-06-24" @default.
- W2100114562 creator A5022406366 @default.
- W2100114562 creator A5040578557 @default.
- W2100114562 date "2014-07-15" @default.
- W2100114562 modified "2023-10-01" @default.
- W2100114562 title "Versatile coordination chemistry of a bis(methyliminophosphoranyl)pyridine ligand on copper centres" @default.
- W2100114562 cites W1964284609 @default.
- W2100114562 cites W1967476900 @default.
- W2100114562 cites W1969635440 @default.
- W2100114562 cites W1973164200 @default.
- W2100114562 cites W1973561203 @default.
- W2100114562 cites W1975830545 @default.
- W2100114562 cites W1980743035 @default.
- W2100114562 cites W1986267883 @default.
- W2100114562 cites W1988091937 @default.
- W2100114562 cites W1989333395 @default.
- W2100114562 cites W1994671258 @default.
- W2100114562 cites W1998368720 @default.
- W2100114562 cites W2002385333 @default.
- W2100114562 cites W2003943583 @default.
- W2100114562 cites W2004988575 @default.
- W2100114562 cites W2005560880 @default.
- W2100114562 cites W2011307683 @default.
- W2100114562 cites W2016767746 @default.
- W2100114562 cites W2018260754 @default.
- W2100114562 cites W2018439502 @default.
- W2100114562 cites W2020102842 @default.
- W2100114562 cites W2022524151 @default.
- W2100114562 cites W2028751656 @default.
- W2100114562 cites W2044370747 @default.
- W2100114562 cites W2047049197 @default.
- W2100114562 cites W2054772282 @default.
- W2100114562 cites W2055516290 @default.
- W2100114562 cites W2060033998 @default.
- W2100114562 cites W2061055390 @default.
- W2100114562 cites W2062896630 @default.
- W2100114562 cites W2063452051 @default.
- W2100114562 cites W2072510291 @default.
- W2100114562 cites W2073881108 @default.
- W2100114562 cites W2073914478 @default.
- W2100114562 cites W2076095926 @default.
- W2100114562 cites W2076194716 @default.
- W2100114562 cites W2079054670 @default.
- W2100114562 cites W2079085448 @default.
- W2100114562 cites W2080694253 @default.
- W2100114562 cites W2081542570 @default.
- W2100114562 cites W2084944709 @default.
- W2100114562 cites W2087524611 @default.
- W2100114562 cites W2089021470 @default.
- W2100114562 cites W2095090592 @default.
- W2100114562 cites W2095474273 @default.
- W2100114562 cites W2096556396 @default.
- W2100114562 cites W2099037802 @default.
- W2100114562 cites W2101349044 @default.
- W2100114562 cites W2102983340 @default.
- W2100114562 cites W2103029770 @default.
- W2100114562 cites W2110408997 @default.
- W2100114562 cites W2111851308 @default.
- W2100114562 cites W2112806931 @default.
- W2100114562 cites W2115551787 @default.
- W2100114562 cites W2123639344 @default.
- W2100114562 cites W2127076481 @default.
- W2100114562 cites W2132291425 @default.
- W2100114562 cites W2133320381 @default.
- W2100114562 cites W2139009932 @default.
- W2100114562 cites W2145662716 @default.
- W2100114562 cites W2147272538 @default.
- W2100114562 cites W2148472965 @default.
- W2100114562 cites W2149950528 @default.
- W2100114562 cites W2162290474 @default.
- W2100114562 cites W2168439556 @default.
- W2100114562 cites W2312994186 @default.
- W2100114562 cites W2316125765 @default.
- W2100114562 cites W2316171149 @default.
- W2100114562 cites W2323910476 @default.
- W2100114562 cites W2324282546 @default.
- W2100114562 cites W2328858925 @default.
- W2100114562 cites W2330182345 @default.
- W2100114562 cites W2332954213 @default.
- W2100114562 cites W2949566627 @default.
- W2100114562 cites W2949573330 @default.
- W2100114562 cites W2951077418 @default.
- W2100114562 cites W2952914889 @default.
- W2100114562 cites W2953350104 @default.
- W2100114562 doi "https://doi.org/10.1039/c4dt01794c" @default.
- W2100114562 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25076168" @default.
- W2100114562 hasPublicationYear "2014" @default.
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