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- W2100407710 abstract "The NMR spectra (chiefly 1H) of isomeric 2,5- and 2,3-dimethyl-4-phenyl-4-piperidinols, related esters and trans- 2,6-dimethyl-4-propionyloxy-4-phenylpiperidine HCl (all N-methylated) have been assigned and analysed in terms of solute conformation. Preferred forms include 4-ax-phenyl and 4-eq-phenyl chairs and, in the case of the γ-2,3-dimethyl-4-piperidinol base, a boat conformation. In several cases the existence of pairs of N-protonated epimers has been demonstrated. The findings are important both to the conformational analysis of saturated six-membered heterocycles and to stereoactivity analyses of opioid ligands of the 4-arylpiperidine class." @default.
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- W2100407710 date "1992-10-01" @default.
- W2100407710 modified "2023-09-27" @default.
- W2100407710 title "The solute conformation of opioid ligands of the 4-arylpiperidine class: α-Promedol and related compounds" @default.
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- W2100407710 doi "https://doi.org/10.1002/mrc.1260301011" @default.
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