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- W2100589048 abstract "A facile and efficient approach was developed to simultaneously functionalize and reduce graphene oxide (GO) with p-phenylene diamine (PPD) by simple refluxing. This was possible by the nucleophilic substitution reaction of epoxide groups of GO with amine groups of PPD aided by NH(3) solution. As a consequence, electrical conductivity of GO-PPD increased to 2.1 × 10(2) S/m, which was nearly 9 orders of magnitude higher than that of GO. Additionally, after the incorporation of GO-PPD in polystyrene (PS), the composites exhibited a sharp transition from electrically insulating to conducting behavior with a low percolation threshold of ~0.34 vol %, which was attributed to the improved dispersion and the reduction of GO-PPD. Thermal stability of the PS/GO-PPD composite was also ~8 °C higher than that of PS." @default.
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- W2100589048 date "2012-03-26" @default.
- W2100589048 modified "2023-10-17" @default.
- W2100589048 title "Functionalization and Reduction of Graphene Oxide with <i>p</i>-Phenylene Diamine for Electrically Conductive and Thermally Stable Polystyrene Composites" @default.
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- W2100589048 doi "https://doi.org/10.1021/am201654b" @default.
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