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- W2100633260 abstract "The vibration-rotation spectrum of vinyl fluoride has been investigated in the v 4 band region around 1656 cm-1 at a resolution of about 0·003 cm-1 using a Fourier transform infrared spectrometer. This fundamental of symmetry species A′ is mainly affected by first-order b-Coriolis resonance with the close-lying v 8 + v 12 and 2v 9 + v 12 levels. The rovibrational analysis led to the identification of about 2000 lines with J ˇ- 58 and K a ˇ- 16 of the predominant a-type component. Using Watson's A-reduction Hamiltonian in the I r representation, a set of effective constants for the v 4 band was obtained employing transitions free of major resonance contribution. Even though no direct transitions to the perturbing levels have been observed, the determination of a few constants for the perturber v 8 + v 12 has been achieved." @default.
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- W2100633260 date "1996-02-20" @default.
- W2100633260 modified "2023-09-28" @default.
- W2100633260 title "A Fourier transform infrared study of CH2=CHF in thev4band region near 1650 cm-1" @default.
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- W2100633260 doi "https://doi.org/10.1080/00268979600100401" @default.
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