Matches in SemOpenAlex for { <https://semopenalex.org/work/W2100641515> ?p ?o ?g. }
- W2100641515 endingPage "8102" @default.
- W2100641515 startingPage "8096" @default.
- W2100641515 abstract "A three-step cascade reaction involving a water-accelerated catalytic carboalumination, a Claisen rearrangement, and a nucleophilic carbonyl addition converts terminal alkynes and allyl vinyl ethers into allylic alcohols containing up to three contiguous asymmetric carbon centers. Stoichiometric quantities of water as an additive increase the rate of the [3,3] sigmatropic rearrangement as well as the diastereoselectivity of the carbonyl addition process. Reaction products contain 1,6-diene functionalities that are readily cyclized to substituted cyclopentenes. An extension of this methodology to a sequence involving a [1,3] sigmatropic shift was feasible with a cyclopropylmethyl vinyl ether substrate." @default.
- W2100641515 created "2016-06-24" @default.
- W2100641515 creator A5018024103 @default.
- W2100641515 creator A5050500168 @default.
- W2100641515 creator A5091461042 @default.
- W2100641515 date "2005-09-01" @default.
- W2100641515 modified "2023-10-18" @default.
- W2100641515 title "Transition-Metal-Mediated Cascade Reactions: The Water-Accelerated Carboalumination−Claisen Rearrangement−Carbonyl Addition Reaction" @default.
- W2100641515 cites W1966242825 @default.
- W2100641515 cites W1967621311 @default.
- W2100641515 cites W1969335186 @default.
- W2100641515 cites W1978595856 @default.
- W2100641515 cites W1984828194 @default.
- W2100641515 cites W2000282113 @default.
- W2100641515 cites W2003844051 @default.
- W2100641515 cites W2008146632 @default.
- W2100641515 cites W2013301345 @default.
- W2100641515 cites W2019515493 @default.
- W2100641515 cites W2027173246 @default.
- W2100641515 cites W2032102338 @default.
- W2100641515 cites W2040230919 @default.
- W2100641515 cites W2044654623 @default.
- W2100641515 cites W2045017111 @default.
- W2100641515 cites W2046418441 @default.
- W2100641515 cites W2056079059 @default.
- W2100641515 cites W2060610140 @default.
- W2100641515 cites W2064737932 @default.
- W2100641515 cites W2069483578 @default.
- W2100641515 cites W2071877397 @default.
- W2100641515 cites W2074373402 @default.
- W2100641515 cites W2079605693 @default.
- W2100641515 cites W2083924613 @default.
- W2100641515 cites W2084911049 @default.
- W2100641515 cites W2087211246 @default.
- W2100641515 cites W2092683043 @default.
- W2100641515 cites W2093229567 @default.
- W2100641515 cites W2094500075 @default.
- W2100641515 cites W2107630437 @default.
- W2100641515 cites W2111677437 @default.
- W2100641515 cites W2117739721 @default.
- W2100641515 cites W2120791056 @default.
- W2100641515 cites W2123670835 @default.
- W2100641515 cites W2125688283 @default.
- W2100641515 cites W2128558953 @default.
- W2100641515 cites W2158384381 @default.
- W2100641515 cites W2164145469 @default.
- W2100641515 cites W2164663848 @default.
- W2100641515 cites W2170517170 @default.
- W2100641515 cites W2175058752 @default.
- W2100641515 cites W2314598258 @default.
- W2100641515 cites W2324927567 @default.
- W2100641515 cites W2328710607 @default.
- W2100641515 cites W2607140987 @default.
- W2100641515 cites W2950399441 @default.
- W2100641515 cites W2950507086 @default.
- W2100641515 cites W2950563882 @default.
- W2100641515 cites W2950685254 @default.
- W2100641515 cites W2951000101 @default.
- W2100641515 cites W2951469433 @default.
- W2100641515 cites W2952128965 @default.
- W2100641515 cites W2952149134 @default.
- W2100641515 cites W2952356705 @default.
- W2100641515 cites W2952666453 @default.
- W2100641515 cites W2952970946 @default.
- W2100641515 cites W4211079585 @default.
- W2100641515 cites W4211254635 @default.
- W2100641515 cites W4213147052 @default.
- W2100641515 cites W4236063685 @default.
- W2100641515 cites W4254306029 @default.
- W2100641515 doi "https://doi.org/10.1021/jo051211v" @default.
- W2100641515 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16277333" @default.
- W2100641515 hasPublicationYear "2005" @default.
- W2100641515 type Work @default.
- W2100641515 sameAs 2100641515 @default.
- W2100641515 citedByCount "35" @default.
- W2100641515 countsByYear W21006415152012 @default.
- W2100641515 countsByYear W21006415152013 @default.
- W2100641515 countsByYear W21006415152014 @default.
- W2100641515 countsByYear W21006415152015 @default.
- W2100641515 countsByYear W21006415152016 @default.
- W2100641515 countsByYear W21006415152017 @default.
- W2100641515 countsByYear W21006415152018 @default.
- W2100641515 countsByYear W21006415152020 @default.
- W2100641515 countsByYear W21006415152021 @default.
- W2100641515 countsByYear W21006415152022 @default.
- W2100641515 countsByYear W21006415152023 @default.
- W2100641515 crossrefType "journal-article" @default.
- W2100641515 hasAuthorship W2100641515A5018024103 @default.
- W2100641515 hasAuthorship W2100641515A5050500168 @default.
- W2100641515 hasAuthorship W2100641515A5091461042 @default.
- W2100641515 hasConcept C120095180 @default.
- W2100641515 hasConcept C155647269 @default.
- W2100641515 hasConcept C161790260 @default.
- W2100641515 hasConcept C178790620 @default.
- W2100641515 hasConcept C178907741 @default.
- W2100641515 hasConcept C185592680 @default.
- W2100641515 hasConcept C20774148 @default.
- W2100641515 hasConcept C2780407432 @default.