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- W2100787091 abstract "Calixarenes can be used to promote the self-assembly of thermoremanent cobalt nanoparticles into bracelet-like rings below 100 nm in diameter. These kinetically stable assemblies are regulated by the equilibrium between enthalpic gain (dipole–dipole and long-range van der Waals interactions) and entropic loss, analogous to the thermodynamic balance of forces governing supramolecular self-assembly. Examination of the Co nanoparticle rings by electron holography (an electron microscopy technique for imaging in-plane magnetic induction) reveals the existence of chiral flux closure (FC) domains at room temperature, comprising a ‘racemic’ mixture of clockwise and anticlockwise states. Furthermore, these FC polarisations can be reversed by applying out-of-plane magnetic pulses (H z ) in alternating directions. This switching behaviour has no known analogy at the macroscopic level, and may represent a uniquely nanoscale phenomenon." @default.
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- W2100787091 date "2009-04-01" @default.
- W2100787091 modified "2023-09-23" @default.
- W2100787091 title "Calixarene-stabilised cobalt nanoparticle rings: Self-assembly and collective magnetic properties" @default.
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- W2100787091 doi "https://doi.org/10.1080/10610270802546044" @default.
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