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- W2100800865 abstract "Abstract The addition of anhydrous cerium chloride to nitrile aldol reactions has been found to provide high yields of β-hydroxynitriles. Also, the aldol reaction of α,β-unsaturated carbonyl compounds with nitrile enolates in the presence of cerium chloride affords 1, 2 addition exclusively in good to excellent yields. The organocerium complexes of R-(+)-1,1′-bi-2-naphthol have successfully mediated the aldol addition of lithio alkyl and arylacetonitriles to aldehydes, and the reaction gives β-hydroxynitriles in good yields with moderate to good diastereoselectivity." @default.
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- W2100800865 date "1998-04-01" @default.
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- W2100800865 title "Cerium (III) chloride mediated nitrile aldol reactions: Enhanced diastereoselectivities using a chiral organocerium complex" @default.
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