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• W2100909095 endingPage "4572" @default.
• W2100909095 startingPage "4568" @default.
• W2100909095 abstract "Abstract CC bond formation is the most fundamental way for the chain propagation in organic molecules. This achievement through tandem oxidation of two different CH bonds represents the state of the art in organic synthesis. Selective functionalization of the ubiquitous aliphatic CH bonds offers an attractive option for this oxidative cross‐coupling methodology. To develop such a methodology under mild and “metal‐free” conditions remains challenging. Herein, we report hypervalent iodine‐mediated selective oxidative functionalization of aliphatic CH bonds of alkanes with chromones and (thio)chromones. A wide range of alkanes, both cyclic and acyclic, has been found to react selectively and predictably in good yields. The developed methodology is also the first report of a direct oxidative functionalization of the C‐2 position of (thio)chromones with alkanes to access bioactive compounds." @default.
• W2100909095 created "2016-06-24" @default.
• W2100909095 creator A5051708585 @default.
• W2100909095 creator A5079953944 @default.
• W2100909095 date "2014-03-06" @default.
• W2100909095 modified "2023-10-18" @default.
• W2100909095 title "Hypervalent Iodine-Mediated Selective Oxidative Functionalization of (Thio)chromones with Alkanes" @default.
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