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- W2101074920 abstract "The syntheses and characterizations of mixed-cation fluorosulfates containing AgII ions are reported and add to the moderately well-known chemistry of AgII compounds. The compounds synthesized mostly show different structures and compositions. The mixed sodium–silver fluorosulfate is isostructural with Ag3(SO3F)4 (monoclinic P21/c, a = 5.2812 A, b = 13.0473 A, c = 19.3557 A, and β = 100.970°) and has the composition (Ag0.05Na0.95)(Ag0.65Na0.35)AgII(SO3F)4. The mixed potassium–silver fluorosulfate does not correspond to KI2AgII(SO3F)4 but rather to KAgI2AgII(SO3F)5 [orthorhombic P2221, a = 6.4736(3) A, b = 7.3915(4) A, and c = 17.7736(10) A]. Two rubidium–silver fluorosulfates form as a mixture, one corresponds to RbAgI2AgII(SO3F)5 [orthorhombic P2221, a = 6.4828(6) A, b = 7.3551(7) A, c = 18.0262(17) A], and the other corresponds to RbAgII(SO3F)3 [monoclinic P21/m, a = 15.8152(14) A, b = 15.4861(13) A, c = 17.0211(14) A, and β = 101.513(5)°]. The cesium fluorosulfate/silver(II) fluorosulfate phase diagram is exemplified by the CsAgII(SO3F)3 salt [triclinic P, a = 14.9241(5) A, b = 9.7046(3) A, c = 17.8465(7) A, α = 109.116(2)°, β = 84.655(3)°, and γ = 119.171(3)°]. The IR and Raman spectra of the compounds were measured, and their thermal stability and magnetic properties have been determined. The MAgI2AgII(SO3F)5 systems show antiferromagnetic behavior with absolute superexchange constants of up to 19.1 meV for M = K, and ferromagnetism can be observed below 20–40 K for the MAg(SO3F)3 derivatives (M = Rb, Cs)." @default.
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- W2101074920 date "2014-12-02" @default.
- W2101074920 modified "2023-10-17" @default.
- W2101074920 title "Unexpectedly Complex Crystalline Phases in the MSO3F-Ag(SO3F)2Phase Diagram (M = Na, K, Rb, Cs)" @default.
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- W2101074920 doi "https://doi.org/10.1002/ejic.201402948" @default.
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