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- W2101143954 abstract "The formation of a CC and a CN bond in a reaction between γ-(N-arylamino) alkenes and aryl bromides results in the stereoselective synthesis of substituted pyrrolidine derivatives (see scheme). Preliminary studies suggest these reactions proceed by intramolecular alkene insertion into the PdN bond of intermediate [Pd(Ar)(amido)] complexes. dba=dibenzylideneacetone, dppb=1,3-bis(diphenylphosphanyl)butane. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2004/z460060_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W2101143954 date "2004-07-05" @default.
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- W2101143954 title "Palladium-Catalyzed Synthesis ofN-Aryl Pyrrolidines fromγ-(N-Arylamino) Alkenes: Evidence for Chemoselective Alkene Insertion into PdN Bonds" @default.
- W2101143954 doi "https://doi.org/10.1002/anie.200460060" @default.
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