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- W2101443375 abstract "A major concern in sediment capping effectiveness is gas ebullition from organic matter biodegradation in sediments. Gases may open advective channels that can result in substantial pollution release. The aim of this study was to determine the gas ebullition rate in sediments in preparation for construction of an active capping technology demonstration at the Collateral Channel site in the Chicago River. Sediment samples were collected from five sites along a transection of Collateral Channel from the combined sewer outfall at the Channel terminus. Biogenic gas production was measured in samples incubated at 5° to 35° C. Gas production followed a first order reaction trend and Arrhenius plots were obtained to determine the temperature dependence of the kinetic rate. These allowed us to predict gas ebullition for the annual temperature variation in the sediments. CO2/CH4 ratios change with temperature, with lower ratios at lower temperatures suggesting dominance by acetoclastic methanogens. These data were used to select adequate active capping remedial alternatives for the Channel. We conclude that wide variations in gas production occur, necessitating gas capture/control during the elevated temperatures of summer. To achieve this, an innovative geo-mesh material with an overlying highly permeable layer will be employed." @default.
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- W2101443375 date "2007-01-01" @default.
- W2101443375 modified "2023-09-27" @default.
- W2101443375 title "Modeling and Control of Gas Ebullition in Capped Sediments" @default.
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