FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2101473456> ?p ?o ?g. }

• W2101473456 endingPage "17980" @default.
• W2101473456 startingPage "17973" @default.
• W2101473456 abstract "Abstract We present a nitrogen‐containing polycyclic aromatic hydrocarbon (N‐PAH), namely 12‐methoxy‐9‐(4‐methoxyphenyl)‐5,8‐diphenyl‐4‐(pyridin‐4‐yl)pyreno[1,10,9‐ h , i , j ]isoquinoline ( c ‐TPE‐ON), which exhibits high quantum‐yield emission both in solution (blue) and in the solid state (yellow). This molecule was unexpectedly obtained by a three‐fold, highly regioselective photocyclodehydrogenation of a tetraphenylethylene‐derived AIEgen. Based on manifold approaches involving UV/Vis, photoluminescence, and NMR spectroscopy as well as HRMS, we propose a reasonable mechanism for the formation of the disk‐like N‐PAH that is supported by density functional theory calculations. In contrast to most PAHs that are commonly used, our system does not suffer from entire fluorescence quenching in the solid state due to the peripheral aromatic rings preventing π–π stacking interactions, as evidenced by single‐crystal X‐ray analysis. Moreover, its rod‐like microcrystals exhibit excellent optical waveguide properties. Hence, c ‐TPE‐ON comprises a N‐PAH with unprecedented luminescent properties and as such is a promising candidate for fabricating organic optoelectronic devices. Our design and synthetic strategy might lead to a more general approach to the preparation of solution‐ and solid‐state luminescent PAHs." @default.
• W2101473456 created "2016-06-24" @default.
• W2101473456 creator A5001320568 @default.
• W2101473456 creator A5004121907 @default.
• W2101473456 creator A5026381056 @default.
• W2101473456 creator A5033020983 @default.
• W2101473456 creator A5043743472 @default.
• W2101473456 creator A5045394394 @default.
• W2101473456 creator A5051113096 @default.
• W2101473456 creator A5060536474 @default.
• W2101473456 creator A5061451649 @default.
• W2101473456 creator A5065804356 @default.
• W2101473456 creator A5066514515 @default.
• W2101473456 creator A5071196133 @default.
• W2101473456 creator A5087177476 @default.
• W2101473456 creator A5088557049 @default.
• W2101473456 creator A5089379373 @default.
• W2101473456 creator A5089891089 @default.
• W2101473456 date "2015-10-22" @default.
• W2101473456 modified "2023-10-18" @default.
• W2101473456 title "A Luminescent Nitrogen-Containing Polycyclic Aromatic Hydrocarbon Synthesized by Photocyclodehydrogenation with Unprecedented Regioselectivity" @default.
• W2101473456 cites W1152857180 @default.
• W2101473456 cites W1964715330 @default.
• W2101473456 cites W1969409082 @default.
• W2101473456 cites W1971710941 @default.
• W2101473456 cites W1975515814 @default.
• W2101473456 cites W1977029449 @default.
• W2101473456 cites W1978741919 @default.
• W2101473456 cites W1979233690 @default.
• W2101473456 cites W1980078990 @default.
• W2101473456 cites W1984990803 @default.
• W2101473456 cites W1985302810 @default.
• W2101473456 cites W1993908005 @default.
• W2101473456 cites W1994724903 @default.
• W2101473456 cites W1998050972 @default.
• W2101473456 cites W1998700258 @default.
• W2101473456 cites W2001974127 @default.
• W2101473456 cites W2017232207 @default.
• W2101473456 cites W2024189693 @default.
• W2101473456 cites W2032185182 @default.
• W2101473456 cites W2038150324 @default.
• W2101473456 cites W2038742083 @default.
• W2101473456 cites W2040270294 @default.
• W2101473456 cites W2058129958 @default.
• W2101473456 cites W2058957873 @default.
• W2101473456 cites W2064325362 @default.
• W2101473456 cites W2066472853 @default.
• W2101473456 cites W2078409317 @default.
• W2101473456 cites W2082797262 @default.
• W2101473456 cites W2085905950 @default.
• W2101473456 cites W2087206944 @default.
• W2101473456 cites W2088316080 @default.
• W2101473456 cites W2089431813 @default.
• W2101473456 cites W2097864132 @default.
• W2101473456 cites W2098507112 @default.
• W2101473456 cites W2102523740 @default.
• W2101473456 cites W2103890222 @default.
• W2101473456 cites W2105109249 @default.
• W2101473456 cites W2106998892 @default.
• W2101473456 cites W2121170859 @default.
• W2101473456 cites W2122180381 @default.
• W2101473456 cites W2133818281 @default.
• W2101473456 cites W2135739209 @default.
• W2101473456 cites W2137920348 @default.
• W2101473456 cites W2142594455 @default.
• W2101473456 cites W2152417280 @default.
• W2101473456 cites W2159182565 @default.
• W2101473456 cites W2160305838 @default.
• W2101473456 cites W2165344788 @default.
• W2101473456 cites W2169953219 @default.
• W2101473456 cites W2301684422 @default.
• W2101473456 cites W2318468106 @default.
• W2101473456 cites W2322047931 @default.
• W2101473456 cites W2322377290 @default.
• W2101473456 cites W2331631786 @default.
• W2101473456 cites W2949201047 @default.
• W2101473456 cites W2949612939 @default.
• W2101473456 cites W2950734375 @default.
• W2101473456 cites W4236454691 @default.
• W2101473456 cites W4239303349 @default.
• W2101473456 cites W4239833854 @default.
• W2101473456 cites W4240199589 @default.
• W2101473456 cites W4250452686 @default.
• W2101473456 cites W4252165333 @default.
• W2101473456 cites W4254851238 @default.
• W2101473456 cites W4255476722 @default.
• W2101473456 cites W4376848790 @default.
• W2101473456 doi "https://doi.org/10.1002/chem.201503147" @default.
• W2101473456 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/26490877" @default.
• W2101473456 hasPublicationYear "2015" @default.
• W2101473456 type Work @default.
• W2101473456 sameAs 2101473456 @default.
• W2101473456 citedByCount "16" @default.
• W2101473456 countsByYear W21014734562016 @default.
• W2101473456 countsByYear W21014734562017 @default.
• W2101473456 countsByYear W21014734562018 @default.
• W2101473456 countsByYear W21014734562019 @default.
• W2101473456 countsByYear W21014734562020 @default.

• next