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- W2101629717 abstract "The effect of small (micromolar) amounts of chloride on photoelectrochemical properties of oxide layers spontaneously developed in Cu|Cu(II) – glycolic acid system at pH 5.85 was investigated. Potentiometric data obtained under chopped illumination conditions show negative open-circuit photopotentials that are typical of n-type Cu 2 O. The level of the photopotential was found to increase with the intensity and quantum energy of disturbing illumination. The estimated band gap of n-Cu 2 O (~2.2 eV) actually coincides with that obtained for crystalline p-Cu 2 O. Chlorides enhance formation of Cu 2 O, increasing the height of a characteristic current peak. Positive photocurrents were detected at moderate cathodic polarizations. The inversion of the photocurrent sign resulting in n→ p transition was found to occur at a certain potential that depends on oxide layer thickness." @default.
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- W2101629717 date "2006-01-01" @default.
- W2101629717 modified "2023-10-08" @default.
- W2101629717 title "Photoelectrochemical properties of oxide layers developed on copper electrode in Cu(II) solutions containing glycolic acid and small amounts of chloride" @default.
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