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• W2101785219 endingPage "4591" @default.
• W2101785219 startingPage "4584" @default.
• W2101785219 abstract "Methylphosphonate (MP) oligodeoxynucleotides (MPOs) are metabolically stable analogs of conventional DNA containing a methyl group in place of one of the non-bonding phosphoryl oxygens. All 16 possible chiral R P MP dinucleotides were synthesized and derivatized for automated oligonucleotide synthesis. These dimer synthons can be used to prepare (i) all-MP linked oligonucleotides having defined R P chirality at every other position (R P chirally enriched MPOs) or (ii) alternating R P MP/phosphodiester backbone oligonucleotides, depending on the composition of the 3′-coupling group. Chirally pure dimer synthons were also prepared with 2′- O -methyl sugar modifications. Oligonucleotides prepared with these R P chiral methyl-phosphonate" @default.
• W2101785219 created "2016-06-24" @default.
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• W2101785219 date "1996-11-01" @default.
• W2101785219 modified "2023-09-23" @default.
• W2101785219 title "Synthesis and Thermodynamics of Oligonucleotides Containing Chirally Pure RP Methylphosphonate Linkages" @default.
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• W2101785219 doi "https://doi.org/10.1093/nar/24.22.4584" @default.
• W2101785219 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/146287" @default.
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