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• W2101926810 abstract "High yields and high levels of stereocontrol are observed in the oxidative cyclization of vicinal diols using catalytic amounts of a transition metal (see scheme; TFA=trifluoroacetic acid). The product stereochemistry is controlled completely by the starting material, and, importantly, single enantiomers can be accessed readily. The reaction sequence is demonstrated in a very short formal synthesis of the natural product (+)-cis-solamin. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z500513_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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• W2101926810 date "2005-07-18" @default.
• W2101926810 modified "2023-10-16" @default.
• W2101926810 title "Oxidative Cyclization of Diols Derived from 1,5-Dienes: Formation of Enantiopurecis-Tetrahydrofurans by Using Catalytic Osmium Tetroxide; Formal Synthesis of (+)-cis-Solamin" @default.
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• W2101926810 doi "https://doi.org/10.1002/anie.200500513" @default.
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