FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2101977237> ?p ?o ?g. }

• W2101977237 endingPage "2061" @default.
• W2101977237 startingPage "2046" @default.
• W2101977237 abstract "The 2′-cyclopalladated imine complex , reacts with CO in MeOH to afford the 2′-substituted aryl imine 2′-CO2CH3-5′-OCH3C6H3CHNTol (Tol = C6H4-4-CH3). The product of this reaction can be altered by changing the bridging ligand from AcO to Cl, in which case only the 5-membered ring heterocyclic compound is obtained. [Pd(μ-OAc)(1a)]2 with 2 equiv. of Ph3P and CO (1 atm) gives the heterocyclic which arises from two CO insertion reactions, whereas [PdX(1a)]2 (X = AcO, Cl) with 4 equiv. of CNBut and 4 equiv. of Ph2PCH2CH2PPh2 affords the heterocyclic ketenimine [PdCl(1a)]2 reacts with CH2CHCO2CH2CH3 to afford 2′(CHCHCO2CH2CH3)-5′-OCH3C6H3CHO, and [Pd(μ-OAc)(1a)]2 with I2 to give 2′-I-5′-OCH3C6H3CHO. Excess CH3O2CCCCO2CH3 reacts with various substituted cyclopalladated Schiff's bases in MeOH to afford which we formulate as possessing two PdC bonds, and one coordinated ester O atom. The X-ray crystal structure of [Pd(μ-OAc)(1a)]2 has been determined; relevant bond lengths [Å] and bond angles [°] are: PdO(1), 2.139(6), PdO(2), 2.026(6), PdN, 2.039(6), PdC(2′), 1.951(8), PdPd, 3.113(1), NPdC(2′), 80.9(3), NPdO(1), 97.5(2), C(2′)PdO(2), 91.7(3), O(1)PdO(2), 89.2(2)." @default.
• W2101977237 created "2016-06-24" @default.
• W2101977237 creator A5025909367 @default.
• W2101977237 creator A5032820308 @default.
• W2101977237 creator A5037478989 @default.
• W2101977237 date "1985-11-13" @default.
• W2101977237 modified "2023-09-30" @default.
• W2101977237 title "Reactions of Cyclopalladated Benzylidene-aniline<i>Schiff</i>'s Base Complexes. Selective Synthesis of 2′-Substituted<i>Schiff</i>'s Base Derivatives and the X-Ray Crystal Structure of the Dimer [Pd(μ-OAc)(5′-OCH₃C₆H₃CHNC₆H₄-4-CH₃)]₂" @default.
• W2101977237 cites W1519842880 @default.
• W2101977237 cites W1966452647 @default.
• W2101977237 cites W1977166101 @default.
• W2101977237 cites W2014192215 @default.
• W2101977237 cites W2015431308 @default.
• W2101977237 cites W2022063832 @default.
• W2101977237 cites W2033336148 @default.
• W2101977237 cites W2035576674 @default.
• W2101977237 cites W2037103066 @default.
• W2101977237 cites W2043493278 @default.
• W2101977237 cites W2043583611 @default.
• W2101977237 cites W2055812757 @default.
• W2101977237 cites W2057692558 @default.
• W2101977237 cites W2060684253 @default.
• W2101977237 cites W2062309297 @default.
• W2101977237 cites W2075554214 @default.
• W2101977237 cites W2076902862 @default.
• W2101977237 cites W2088149246 @default.
• W2101977237 cites W2091628804 @default.
• W2101977237 cites W2095643658 @default.
• W2101977237 cites W2104155769 @default.
• W2101977237 cites W2164663075 @default.
• W2101977237 cites W2940934176 @default.
• W2101977237 cites W2949675920 @default.
• W2101977237 cites W2950350730 @default.
• W2101977237 cites W2952485866 @default.
• W2101977237 doi "https://doi.org/10.1002/hlca.19850680730" @default.
• W2101977237 hasPublicationYear "1985" @default.
• W2101977237 type Work @default.
• W2101977237 sameAs 2101977237 @default.
• W2101977237 citedByCount "61" @default.
• W2101977237 countsByYear W21019772372013 @default.
• W2101977237 countsByYear W21019772372018 @default.
• W2101977237 countsByYear W21019772372021 @default.
• W2101977237 crossrefType "journal-article" @default.
• W2101977237 hasAuthorship W2101977237A5025909367 @default.
• W2101977237 hasAuthorship W2101977237A5032820308 @default.
• W2101977237 hasAuthorship W2101977237A5037478989 @default.
• W2101977237 hasConcept C115624301 @default.
• W2101977237 hasConcept C116569031 @default.
• W2101977237 hasConcept C120665830 @default.
• W2101977237 hasConcept C121332964 @default.
• W2101977237 hasConcept C135361552 @default.
• W2101977237 hasConcept C155647269 @default.
• W2101977237 hasConcept C161790260 @default.
• W2101977237 hasConcept C170493617 @default.
• W2101977237 hasConcept C178790620 @default.
• W2101977237 hasConcept C185592680 @default.
• W2101977237 hasConcept C207114421 @default.
• W2101977237 hasConcept C2776428424 @default.
• W2101977237 hasConcept C2776464317 @default.
• W2101977237 hasConcept C2776573223 @default.
• W2101977237 hasConcept C2779244968 @default.
• W2101977237 hasConcept C2779546866 @default.
• W2101977237 hasConcept C2780263894 @default.
• W2101977237 hasConcept C2781076698 @default.
• W2101977237 hasConcept C502130503 @default.
• W2101977237 hasConcept C50515024 @default.
• W2101977237 hasConcept C55493867 @default.
• W2101977237 hasConcept C71240020 @default.
• W2101977237 hasConcept C8010536 @default.
• W2101977237 hasConceptScore W2101977237C115624301 @default.
• W2101977237 hasConceptScore W2101977237C116569031 @default.
• W2101977237 hasConceptScore W2101977237C120665830 @default.
• W2101977237 hasConceptScore W2101977237C121332964 @default.
• W2101977237 hasConceptScore W2101977237C135361552 @default.
• W2101977237 hasConceptScore W2101977237C155647269 @default.
• W2101977237 hasConceptScore W2101977237C161790260 @default.
• W2101977237 hasConceptScore W2101977237C170493617 @default.
• W2101977237 hasConceptScore W2101977237C178790620 @default.
• W2101977237 hasConceptScore W2101977237C185592680 @default.
• W2101977237 hasConceptScore W2101977237C207114421 @default.
• W2101977237 hasConceptScore W2101977237C2776428424 @default.
• W2101977237 hasConceptScore W2101977237C2776464317 @default.
• W2101977237 hasConceptScore W2101977237C2776573223 @default.
• W2101977237 hasConceptScore W2101977237C2779244968 @default.
• W2101977237 hasConceptScore W2101977237C2779546866 @default.
• W2101977237 hasConceptScore W2101977237C2780263894 @default.
• W2101977237 hasConceptScore W2101977237C2781076698 @default.
• W2101977237 hasConceptScore W2101977237C502130503 @default.
• W2101977237 hasConceptScore W2101977237C50515024 @default.
• W2101977237 hasConceptScore W2101977237C55493867 @default.
• W2101977237 hasConceptScore W2101977237C71240020 @default.
• W2101977237 hasConceptScore W2101977237C8010536 @default.
• W2101977237 hasIssue "7" @default.
• W2101977237 hasLocation W21019772371 @default.
• W2101977237 hasOpenAccess W2101977237 @default.
• W2101977237 hasPrimaryLocation W21019772371 @default.
• W2101977237 hasRelatedWork W1943450521 @default.
• W2101977237 hasRelatedWork W2036976957 @default.

• next