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- W2101981572 abstract "The compound BaFeO3-x exists in many forms, the hexagonal phase having a wide range in oxygen content (BaFeO2.63–2.92). The other phases have the limited compositions and the distinct structures of perovskite: triclinic I, BaFeO2.50; triclinic II, BaFeO2.64–2.67; rhombohedral I and II, BaFeO2.62–2.64; and tetragonal, BaFeO2.75–2.81. The phases contain Fe4+ ions correlating with the oxygen content. The hexagonal phase shows a continuous change in oxygen content with temperature down to BaFeO2.63. The perovskitelike phases, however, show characteristic transformations. The triclinic I phase oxidizes to the triclinic II form at 320° to 500°C and to the hexagonal form at 720° to 915°C in oxygen. These transformations are related to oxidation-reduction of iron ions (Fe3+⇌ Fe4+)." @default.
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- W2101981572 date "1966-11-01" @default.
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- W2101981572 title "Phase Transformation in Barium Orthoferrate, BaFeO3-x" @default.
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- W2101981572 doi "https://doi.org/10.1111/j.1151-2916.1966.tb13176.x" @default.
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