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• W2101989872 abstract "Hydrogasification of carbon (C + 2H <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2</sub> rarr CH <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>4</sub> ) was studied using a microwave plasma in atmospheric pressure Ar/H <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2</sub> mixtures. When the activated Ar/H <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2</sub> gas stream interacted with cold carbon particles downstream of the microwave cavity, CH <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>4</sub> (methane) was the only stable gasification product, as measured by gas chromatography. However, when carbon particles were injected into the plasma within the microwave cavity, both C <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2</sub> H <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2</sub> (acetylene) and C <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2</sub> H <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>4</sub> (ethylene) were measured in addition to CH <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>4</sub> . To identify a gasification mechanism by the microwave plasma, UV emission and minimum operational power required to maintain plasma were measured. From the experimental results, the initial reaction step leading to CH <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>4</sub> is thought to be a chemisorption-desorption reaction of hydrogen radical onto a carbon particle. For the C <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2</sub> H <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2</sub> and C <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>2</sub> H <sub xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>4</sub> generation, hydrogen ion reaction with a carbon particle is suggested." @default.
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• W2101989872 date "2007-12-01" @default.
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• W2101989872 title "Hydrogasification of Carbon in an Atmospheric Pressure Microwave Plasma" @default.
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• W2101989872 doi "https://doi.org/10.1109/tps.2007.910139" @default.
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