Matches in SemOpenAlex for { <https://semopenalex.org/work/W2101998922> ?p ?o ?g. }
- W2101998922 endingPage "119" @default.
- W2101998922 startingPage "91" @default.
- W2101998922 abstract "Reactions of phosphorus(v) compounds involving the mutual interconversion of tetra- and pentacoordinate species are discussed in a critical review emphasizing stereochemical implications of the reaction mechanism. This discussion includes the formation and decomposition of the stable oxyphosphoranes, the Michaelis-Arbusov, Perkov, and Wittig reactions, interconversions of phosphines and their oxides, and the nucleophilic displacements on phosphonium compounds. Reactions of phosphate esters and related compounds receive particular attention. All chemical arguments are derived by considering the effect of factors determining the relative stabilities of phosphorane derivatives, their rates of formation, decomposition and rearrangement by bond deformation or rupture and recombination processes, considerations which are uniformly applied on the basis of concepts developed in a preceding communication[2]. It is shown that a comprehensive mechanistic interpretation of the foregoing reactions requires substantial addition to available conceptual foundations such that, in many cases, present concepts and mechanisms must be revised." @default.
- W2101998922 created "2016-06-24" @default.
- W2101998922 creator A5047538529 @default.
- W2101998922 creator A5053074928 @default.
- W2101998922 creator A5061906099 @default.
- W2101998922 creator A5088359627 @default.
- W2101998922 date "1973-02-01" @default.
- W2101998922 modified "2023-10-12" @default.
- W2101998922 title "Displacement Reactions of Phosphorus(V) Compounds and Their Pentacoordinate Intermediates" @default.
- W2101998922 cites W102431235 @default.
- W2101998922 cites W1533307517 @default.
- W2101998922 cites W1535979687 @default.
- W2101998922 cites W1592858463 @default.
- W2101998922 cites W1599945665 @default.
- W2101998922 cites W1965912217 @default.
- W2101998922 cites W1967018847 @default.
- W2101998922 cites W1968005625 @default.
- W2101998922 cites W1969924912 @default.
- W2101998922 cites W1973009864 @default.
- W2101998922 cites W1974903485 @default.
- W2101998922 cites W1977002154 @default.
- W2101998922 cites W1980520956 @default.
- W2101998922 cites W1984500097 @default.
- W2101998922 cites W1985684677 @default.
- W2101998922 cites W1986989334 @default.
- W2101998922 cites W1987400021 @default.
- W2101998922 cites W1988928056 @default.
- W2101998922 cites W1994710506 @default.
- W2101998922 cites W1995506236 @default.
- W2101998922 cites W1997162035 @default.
- W2101998922 cites W1997697926 @default.
- W2101998922 cites W2000897470 @default.
- W2101998922 cites W2006913439 @default.
- W2101998922 cites W2008771089 @default.
- W2101998922 cites W2011307689 @default.
- W2101998922 cites W2012677036 @default.
- W2101998922 cites W2013892008 @default.
- W2101998922 cites W2013987631 @default.
- W2101998922 cites W2016147186 @default.
- W2101998922 cites W2016948836 @default.
- W2101998922 cites W2018785105 @default.
- W2101998922 cites W2028543094 @default.
- W2101998922 cites W2031703747 @default.
- W2101998922 cites W2040390402 @default.
- W2101998922 cites W2040641567 @default.
- W2101998922 cites W2045288811 @default.
- W2101998922 cites W2045571314 @default.
- W2101998922 cites W2047568242 @default.
- W2101998922 cites W2047668580 @default.
- W2101998922 cites W2050297657 @default.
- W2101998922 cites W2052160951 @default.
- W2101998922 cites W2053040996 @default.
- W2101998922 cites W2055382443 @default.
- W2101998922 cites W2056635016 @default.
- W2101998922 cites W2059217193 @default.
- W2101998922 cites W2060443743 @default.
- W2101998922 cites W2062029466 @default.
- W2101998922 cites W2063621286 @default.
- W2101998922 cites W2066059215 @default.
- W2101998922 cites W2066219821 @default.
- W2101998922 cites W2066598475 @default.
- W2101998922 cites W2066902114 @default.
- W2101998922 cites W2068729864 @default.
- W2101998922 cites W2071469163 @default.
- W2101998922 cites W2075606155 @default.
- W2101998922 cites W2077241604 @default.
- W2101998922 cites W2078232028 @default.
- W2101998922 cites W2078990341 @default.
- W2101998922 cites W2079451774 @default.
- W2101998922 cites W2079926755 @default.
- W2101998922 cites W2082686263 @default.
- W2101998922 cites W2085234441 @default.
- W2101998922 cites W2087492709 @default.
- W2101998922 cites W2089836448 @default.
- W2101998922 cites W2093316337 @default.
- W2101998922 cites W2094298762 @default.
- W2101998922 cites W2099206557 @default.
- W2101998922 cites W2102414060 @default.
- W2101998922 cites W2126332998 @default.
- W2101998922 cites W2130030475 @default.
- W2101998922 cites W2147922058 @default.
- W2101998922 cites W2170232188 @default.
- W2101998922 cites W2312368595 @default.
- W2101998922 cites W2313768326 @default.
- W2101998922 cites W2313795744 @default.
- W2101998922 cites W2314959767 @default.
- W2101998922 cites W2315007467 @default.
- W2101998922 cites W2315386207 @default.
- W2101998922 cites W2315646710 @default.
- W2101998922 cites W2316167819 @default.
- W2101998922 cites W2317184773 @default.
- W2101998922 cites W2317703722 @default.
- W2101998922 cites W2318154525 @default.
- W2101998922 cites W2318899696 @default.
- W2101998922 cites W2319336768 @default.
- W2101998922 cites W2320519594 @default.
- W2101998922 cites W2320840378 @default.
- W2101998922 cites W2325302691 @default.