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- W2102011004 abstract "Lyngbyaloside C, a classic macrolide, isolated from Lyngbya bouilloni, has shown moderate anticancer activity against several cancer cell lines. Here, we report the first total synthesis and stereochemical configuration reassignment of lyngbyaloside C. The synthesis highlights a one-pot intermolecular ketene esterification reaction to form the crucial tertiary ester and tetrahydropyran. In addition, a novel and concise synthetic pathway towards the 1,3-syn secondary, tertiary diol fragment is described using a regio- and stereospecific electrophilic ether transfer reaction." @default.
- W2102011004 created "2016-06-24" @default.
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- W2102011004 date "2015-06-23" @default.
- W2102011004 modified "2023-10-18" @default.
- W2102011004 title "Total Synthesis and Structural Reassignment of Lyngbyaloside C Highlighted by Intermolecular Ketene Esterification" @default.
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- W2102011004 doi "https://doi.org/10.1002/chem.201502132" @default.
- W2102011004 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/6896800" @default.
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