Matches in SemOpenAlex for { <https://semopenalex.org/work/W2102104934> ?p ?o ?g. }
- W2102104934 endingPage "3008" @default.
- W2102104934 startingPage "3002" @default.
- W2102104934 abstract "Triethylphosphine oxide [(C2H5)3P[double bond, length as m-dash]O; TEPO] was intercalated into protonated Dion-Jacobson-type ion-exchangeable layered perovskites, HLaNb2O7·xH2O (HLaNb) and HCa2Nb3O10·xH2O (HCaNb), by hydrolysis of their n-decoxy derivatives (C10O-HLaNb or C10O-HCaNb) in the presence of TEPO. The interlayer distances of the products (TEPO/C10O-HLaNb and TEPO/C10O-HCaNb) were smaller than those of the corresponding n-decoxy derivatives, but still larger than those of anhydrous protonated forms of HLaNb and HCaNb. The solid-state (31)P NMR signals of the products observed at 94 ppm (TEPO/C10O-HLaNb) and 93 ppm (TEPO/C10O-HCaNb) exhibited large downfield shifts from that of the physisorbed TEPO. IR spectroscopy also showed decreases in the ν(P[double bond, length as m-dash]O) band wavenumbers upon the reactions. These results clearly indicate that TEPO is intercalated and interacted with Brønsted acid sites, the surface hydroxyl groups generated via hydrolysis of n-decoxy groups. The difference in ν(P[double bond, length as m-dash]O) band wavenumbers as well as that in gallery heights suggests that TEPO exhibited different orientations with respect to the inorganic layers. The chemical shifts of solid-state (31)P NMR signals suggested high Brønsted acidity of HLaNb and HCaNb." @default.
- W2102104934 created "2016-06-24" @default.
- W2102104934 creator A5009743433 @default.
- W2102104934 creator A5018447663 @default.
- W2102104934 creator A5029531350 @default.
- W2102104934 creator A5061624340 @default.
- W2102104934 creator A5080580296 @default.
- W2102104934 date "2015-01-01" @default.
- W2102104934 modified "2023-10-15" @default.
- W2102104934 title "Intercalation of triethylphosphine oxide bearing a phosphoryl group into Dion–Jacobson-type ion-exchangeable layered perovskites" @default.
- W2102104934 cites W1918710178 @default.
- W2102104934 cites W1971643816 @default.
- W2102104934 cites W1972196432 @default.
- W2102104934 cites W1974308687 @default.
- W2102104934 cites W1980144680 @default.
- W2102104934 cites W1981356328 @default.
- W2102104934 cites W1985495475 @default.
- W2102104934 cites W1989009155 @default.
- W2102104934 cites W1990020209 @default.
- W2102104934 cites W2002938087 @default.
- W2102104934 cites W2004669139 @default.
- W2102104934 cites W2006903780 @default.
- W2102104934 cites W2009504598 @default.
- W2102104934 cites W2011341199 @default.
- W2102104934 cites W2027203481 @default.
- W2102104934 cites W2029827682 @default.
- W2102104934 cites W2030952714 @default.
- W2102104934 cites W2034151368 @default.
- W2102104934 cites W2043089414 @default.
- W2102104934 cites W2045877499 @default.
- W2102104934 cites W2046875129 @default.
- W2102104934 cites W2048981509 @default.
- W2102104934 cites W2049978540 @default.
- W2102104934 cites W2053177034 @default.
- W2102104934 cites W2060336452 @default.
- W2102104934 cites W2060603292 @default.
- W2102104934 cites W2067254480 @default.
- W2102104934 cites W2070750941 @default.
- W2102104934 cites W2083230631 @default.
- W2102104934 cites W2094147032 @default.
- W2102104934 cites W2100784310 @default.
- W2102104934 cites W2116049427 @default.
- W2102104934 cites W2122922974 @default.
- W2102104934 cites W2313122224 @default.
- W2102104934 cites W2516551511 @default.
- W2102104934 cites W2951500782 @default.
- W2102104934 doi "https://doi.org/10.1039/c4dt02230k" @default.
- W2102104934 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25322439" @default.
- W2102104934 hasPublicationYear "2015" @default.
- W2102104934 type Work @default.
- W2102104934 sameAs 2102104934 @default.
- W2102104934 citedByCount "9" @default.
- W2102104934 countsByYear W21021049342016 @default.
- W2102104934 countsByYear W21021049342017 @default.
- W2102104934 countsByYear W21021049342018 @default.
- W2102104934 countsByYear W21021049342021 @default.
- W2102104934 crossrefType "journal-article" @default.
- W2102104934 hasAuthorship W2102104934A5009743433 @default.
- W2102104934 hasAuthorship W2102104934A5018447663 @default.
- W2102104934 hasAuthorship W2102104934A5029531350 @default.
- W2102104934 hasAuthorship W2102104934A5061624340 @default.
- W2102104934 hasAuthorship W2102104934A5080580296 @default.
- W2102104934 hasConcept C111429119 @default.
- W2102104934 hasConcept C115624301 @default.
- W2102104934 hasConcept C137824038 @default.
- W2102104934 hasConcept C145148216 @default.
- W2102104934 hasConcept C147789679 @default.
- W2102104934 hasConcept C153642686 @default.
- W2102104934 hasConcept C155647269 @default.
- W2102104934 hasConcept C155860418 @default.
- W2102104934 hasConcept C178790620 @default.
- W2102104934 hasConcept C179104552 @default.
- W2102104934 hasConcept C185592680 @default.
- W2102104934 hasConcept C188027245 @default.
- W2102104934 hasConcept C2779851234 @default.
- W2102104934 hasConcept C30095370 @default.
- W2102104934 hasConcept C68381374 @default.
- W2102104934 hasConcept C71240020 @default.
- W2102104934 hasConcept C8010536 @default.
- W2102104934 hasConcept C94412978 @default.
- W2102104934 hasConceptScore W2102104934C111429119 @default.
- W2102104934 hasConceptScore W2102104934C115624301 @default.
- W2102104934 hasConceptScore W2102104934C137824038 @default.
- W2102104934 hasConceptScore W2102104934C145148216 @default.
- W2102104934 hasConceptScore W2102104934C147789679 @default.
- W2102104934 hasConceptScore W2102104934C153642686 @default.
- W2102104934 hasConceptScore W2102104934C155647269 @default.
- W2102104934 hasConceptScore W2102104934C155860418 @default.
- W2102104934 hasConceptScore W2102104934C178790620 @default.
- W2102104934 hasConceptScore W2102104934C179104552 @default.
- W2102104934 hasConceptScore W2102104934C185592680 @default.
- W2102104934 hasConceptScore W2102104934C188027245 @default.
- W2102104934 hasConceptScore W2102104934C2779851234 @default.
- W2102104934 hasConceptScore W2102104934C30095370 @default.
- W2102104934 hasConceptScore W2102104934C68381374 @default.
- W2102104934 hasConceptScore W2102104934C71240020 @default.
- W2102104934 hasConceptScore W2102104934C8010536 @default.
- W2102104934 hasConceptScore W2102104934C94412978 @default.