FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2102110758> ?p ?o ?g. }

• W2102110758 endingPage "433" @default.
• W2102110758 startingPage "433" @default.
• W2102110758 abstract "A new scorpionate borate ligand K[HB(7-azain)3] (1, 7-azain = 7-azaindolyl) has been obtained from the reaction of KBH4 with excess 7-azaindole. The scorpionate ligand 1 was found to be able to form complexes with ZnII and CuI ions. Complex 2 with the formula [BH(7-azain)3](ZnCl) has been obtained from the reaction of ZnCl2 with 1. Complex 3 with the formula [BH(7-azain)3][Cu(PPh3)] has been obtained from the reaction of [Cu(PPh3)2(CH3CN)2][BF4] with 1. The crystal structures of 1–3 have been determined by single-crystal X-ray diffraction analyses which revealed that 1 has a dimeric structure linked together by two K+ ions, 2 has a symmetric tripodal structure with all three 7-azaindolyl groups being coordinated to the ZnII center, and 3 has an asymmetric structure with two of the 7-azaindolyl groups being coordinated to the CuI center and the third 7-azaindolyl group uncoordinated. Variable temperature 1H NMR experiments established that 3 is highly dynamic in solution involving a rapid exchange between the coordinated and the non-coordinated 7-azaindolyl groups. All three compounds display blue emission in the solid state at ambient temperature. However, in solution at ambient temperature, compounds 1 and 2 display bright blue emission while compound 3 has no emission at all. At 77 K, solutions of all three compounds display blue-green phosphorescent emission with a long decay lifetime (> 2 ms)." @default.
• W2102110758 created "2016-06-24" @default.
• W2102110758 creator A5057524603 @default.
• W2102110758 creator A5058875521 @default.
• W2102110758 creator A5063169585 @default.
• W2102110758 creator A5069565621 @default.
• W2102110758 date "2005-01-01" @default.
• W2102110758 modified "2023-10-14" @default.
• W2102110758 title "Cu(i) and Zn(ii) complexes of 7-azaindole-containing scorpionates: Structures, luminescence and fluxionality" @default.
• W2102110758 cites W1494817587 @default.
• W2102110758 cites W1966727243 @default.
• W2102110758 cites W1967111983 @default.
• W2102110758 cites W1970471420 @default.
• W2102110758 cites W1975666963 @default.
• W2102110758 cites W1986796207 @default.
• W2102110758 cites W1996778213 @default.
• W2102110758 cites W2004343680 @default.
• W2102110758 cites W2004535216 @default.
• W2102110758 cites W2018946699 @default.
• W2102110758 cites W2038033009 @default.
• W2102110758 cites W2039793559 @default.
• W2102110758 cites W2044760112 @default.
• W2102110758 cites W2051626358 @default.
• W2102110758 cites W2055704615 @default.
• W2102110758 cites W2059113453 @default.
• W2102110758 cites W2073962785 @default.
• W2102110758 cites W2082233444 @default.
• W2102110758 cites W2082490798 @default.
• W2102110758 cites W2084078332 @default.
• W2102110758 cites W2091501139 @default.
• W2102110758 cites W2094145646 @default.
• W2102110758 cites W2095531445 @default.
• W2102110758 cites W2114482348 @default.
• W2102110758 cites W2144031275 @default.
• W2102110758 cites W2148062424 @default.
• W2102110758 cites W2332197269 @default.
• W2102110758 cites W3136449324 @default.
• W2102110758 doi "https://doi.org/10.1039/b414328k" @default.
• W2102110758 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15672185" @default.
• W2102110758 hasPublicationYear "2005" @default.
• W2102110758 type Work @default.
• W2102110758 sameAs 2102110758 @default.
• W2102110758 citedByCount "5" @default.
• W2102110758 countsByYear W21021107582015 @default.
• W2102110758 countsByYear W21021107582017 @default.
• W2102110758 countsByYear W21021107582018 @default.
• W2102110758 countsByYear W21021107582019 @default.
• W2102110758 countsByYear W21021107582023 @default.
• W2102110758 crossrefType "journal-article" @default.
• W2102110758 hasAuthorship W2102110758A5057524603 @default.
• W2102110758 hasAuthorship W2102110758A5058875521 @default.
• W2102110758 hasAuthorship W2102110758A5063169585 @default.
• W2102110758 hasAuthorship W2102110758A5069565621 @default.
• W2102110758 hasConcept C107814960 @default.
• W2102110758 hasConcept C115624301 @default.
• W2102110758 hasConcept C116569031 @default.
• W2102110758 hasConcept C121332964 @default.
• W2102110758 hasConcept C145148216 @default.
• W2102110758 hasConcept C147789679 @default.
• W2102110758 hasConcept C148869448 @default.
• W2102110758 hasConcept C170493617 @default.
• W2102110758 hasConcept C178790620 @default.
• W2102110758 hasConcept C181817918 @default.
• W2102110758 hasConcept C185592680 @default.
• W2102110758 hasConcept C192562407 @default.
• W2102110758 hasConcept C49040817 @default.
• W2102110758 hasConcept C55493867 @default.
• W2102110758 hasConcept C62520636 @default.
• W2102110758 hasConcept C71240020 @default.
• W2102110758 hasConcept C73922627 @default.
• W2102110758 hasConcept C75473681 @default.
• W2102110758 hasConcept C8010536 @default.
• W2102110758 hasConcept C91881484 @default.
• W2102110758 hasConceptScore W2102110758C107814960 @default.
• W2102110758 hasConceptScore W2102110758C115624301 @default.
• W2102110758 hasConceptScore W2102110758C116569031 @default.
• W2102110758 hasConceptScore W2102110758C121332964 @default.
• W2102110758 hasConceptScore W2102110758C145148216 @default.
• W2102110758 hasConceptScore W2102110758C147789679 @default.
• W2102110758 hasConceptScore W2102110758C148869448 @default.
• W2102110758 hasConceptScore W2102110758C170493617 @default.
• W2102110758 hasConceptScore W2102110758C178790620 @default.
• W2102110758 hasConceptScore W2102110758C181817918 @default.
• W2102110758 hasConceptScore W2102110758C185592680 @default.
• W2102110758 hasConceptScore W2102110758C192562407 @default.
• W2102110758 hasConceptScore W2102110758C49040817 @default.
• W2102110758 hasConceptScore W2102110758C55493867 @default.
• W2102110758 hasConceptScore W2102110758C62520636 @default.
• W2102110758 hasConceptScore W2102110758C71240020 @default.
• W2102110758 hasConceptScore W2102110758C73922627 @default.
• W2102110758 hasConceptScore W2102110758C75473681 @default.
• W2102110758 hasConceptScore W2102110758C8010536 @default.
• W2102110758 hasConceptScore W2102110758C91881484 @default.
• W2102110758 hasIssue "3" @default.
• W2102110758 hasLocation W21021107581 @default.
• W2102110758 hasLocation W21021107582 @default.
• W2102110758 hasOpenAccess W2102110758 @default.
• W2102110758 hasPrimaryLocation W21021107581 @default.

• next