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- W2102210357 abstract "The “phase behavior” of chlorophyll a‘ (Chl a‘, C132-epimer of Chl a) dissolved in aqueous methanol was examined in terms of the composition of the solvent. This study aimed at elucidating the property of Chl a‘, the exotic pigment found in a photosynthetic reaction center complex, as well as at clarifying the nature of the Chl aggregation in aqueous media. Visible absorption, circular dichroism (CD), fluorescence and resonance Raman spectroscopies, dynamic light-scattering measurements, and electron microscopy were utilized. Chl a‘ formed either of two types of colloids depending on the solvent composition. The one formed over a wide methanol volume percentage (ca. 73−30%) commonly possessed a single microscopic structural unit that yielded the double-peaked absorption (ca. 690 and 715 nm) accompanied by a symmetric dispersed-type CD spectrum. Increasing methanol concentration within this solvent composition range enhanced the size of the colloid and finally caused critical opalescence, which was reminis..." @default.
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- W2102210357 date "2010-08-03" @default.
- W2102210357 modified "2023-10-05" @default.
- W2102210357 title "ChemInform Abstract: Spectral Characteristics and Colloidal Properties of Chlorophyll a′ in Aqueous Methanol." @default.
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- W2102210357 doi "https://doi.org/10.1002/chin.199728148" @default.
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