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- W2102383006 abstract "We have studied the electron paramagnetic resonance (EPR) of a single crystal of the CuK2(SO4)2·6H2O Tutton salt when rotated around a and c∗ axes, and around β(≡b) and γ axes at X-band and room temperature. When the static magnetic field lies in the (a, c) plane, both Cu2+ ions are magnetically equivalent and EPR spectrum reduces to a singlet whose shape varies considerably, from a quasi-Lorentzian lineshape following the c axis, to an intermediate (between Gaussian and Lorentzian) lineshape following the a axis. For other orientations of the static magnetic field, the two Cu2+ ions are magnetically unequivalent and the EPR spectrum is a moreorless resolved doublet. When the static magnetic field is parallel to a tetragonal axis, the EPR spectrum is a perfectly resolved doublet, revealing a very weak exchange interaction (J′) between dissimilar ions. For the compound under study, the computer simulation of the EPR spectrum was carried out by adopting a convolution for the shape of the elementary line. This reveals that the exchange interaction between dissimilar ions is vanishingly small at room temperature at an accuracy of 0.0002 cm−1." @default.
- W2102383006 created "2016-06-24" @default.
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- W2102383006 date "1994-11-01" @default.
- W2102383006 modified "2023-09-25" @default.
- W2102383006 title "Vanishing exchange coupling between dissimilar copper ions in CuK2(SO4)2·6H2O as evidenced by X-band electron paramagnetic resonance" @default.
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- W2102383006 doi "https://doi.org/10.1016/0022-3697(94)90211-9" @default.
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