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- W2102433830 abstract "Abstract The solution properties of a hexaimino cryptand containing 2,6-diiminopyridyl units have been investigated by NMR, UV-VIS absorption and luminescence spectroscopy. The difference in the NMR and UV spectra of the Ba2- complex and the cryptand is attributed to the conformational change of the diiminopyridyl group. The luminescence spectra of the compounds show near-UV bands and unexpected low-energy bands. The former is attributed to the normal π-π* transition, while the origin of the low-energy bands is discussed in terms of inter- and intra-molecular aromatic-aromatic interactions. The inter-molecular interaction is important in the free ligand, however, intra-molecular interaction is suggested in the Ba2+ complex. Further, the specific conformational change of the Ba2- complex in DMSO-acetonitrile solution is investigated by the measurements of the stability constant of the Ba2+ complex in various DMSO concentrations. The large decrease over 4.0 in logK is found only for the Ba2+ complex. The be..." @default.
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- W2102433830 date "1996-05-01" @default.
- W2102433830 modified "2023-09-23" @default.
- W2102433830 title "A cryptand containing three diiminopyridyl units; aromatic-aromatic interaction and the stability of the complexes" @default.
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- W2102433830 doi "https://doi.org/10.1080/10610279608035192" @default.
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