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- W2102457560 abstract "A new area of boron-nitrogen chemistry has developed within the last decade. The basis of this area of investigation, involving B—N—C heterocyclic systems, has been characterized through studies by Goubbau and coworkers3’ 4. In 1955 they prepared 1,3,2-diazaboraeycloalkanes illustrating that it is possible to incorporate boron and nitrogen adjacent to each other in a B—N—C ring system in which all annular atoms are σ-bonded to each other3. The primary aim of this work was to elucidate the resonance relations in cyclic aminoborane systems. However, the boron analog of indole, 2-methyl-1,3,2-benzodiazaborolidine, which was prepared in 19574, can be considered the first known heteroaromatic boron-nitrogen compound. In 1958 Dewah initiated studies of heteroaromatic compounds in which an aromatic C—C grouping is replaced by the isoelectronic B—N combination. In the following presentation, heteroaromatics will be limited to the six-membered cyclic derivatives." @default.
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- W2102457560 date "1965-01-01" @default.
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- W2102457560 title "Heterocyclic σ-Bonded Systems Containing Boron and Nitrogen" @default.
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