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• W2102464022 abstract "A series of mono- and disubstituted diiron complexes [(μ-pdt)Fe2(CO)5L] [pdt = 1,3-propanedithiolato; L = PMe3 (2), PMe2Ph (3PPh3 (4), P(OEt)3 (5)] and [(μ-pdt)Fe2(CO)4L2] [L = PMe2Ph (6), PPh3 (7), P(OEt)3 (8)] were prepared as Fe-only hydrogenase-active-site models by controllable CO displacement of [(μ-pdt)Fe2(CO)6] by tertiary phosphanes. The coordination configurations of 3–6 were characterized by X-ray crystallography. Disubstituted diiron complex 6 features an apical/apical coordination mode, instead of the typical transoid basal/basal configuration. The electrochemistry of 2–6 and 8 was studied by cyclic voltammetry to evaluate the effects of different tertiary phosphane ligands on the redox properties of the iron atoms of model complexes. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)" @default.
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• W2102464022 date "2005-06-01" @default.
• W2102464022 modified "2023-10-16" @default.
• W2102464022 title "Influence of Tertiary Phosphanes on the Coordination Configurations and Electrochemical Properties of Iron Hydrogenase Model Complexes: Crystal Structures of [(μ‐S ₂ C ₃ H ₆ )Fe ₂ (CO) _{6– <i>n</i>} L <i> _n </i> ] (L = PMe ₂ Ph, <i>n</i> = 1, 2; PPh ₃ , P(OEt) ₃ , <i>n</i> = 1)" @default.
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• W2102464022 doi "https://doi.org/10.1002/ejic.200400947" @default.
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