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• W2102551061 abstract "Complementary hydrogen-bonding interactions between a barbituric acid-substituted fullerene derivative (1) and corresponding receptor (2) bearing thienylenevinylene units are used to assemble a 1:1 supramolecular complex (K = 5500 M-1). Due to the close proximity of the redox-active moieties within the assembly, strong ground-state electron−donor−acceptor interactions are observed. Photoinduced electron transfer from electron-rich thienylenevinylene subunits to the fullerene is very fast (ket = 5.5 × 1012 s-1), as determined by fs-time-resolved transient absorption spectroscopy." @default.
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• W2102551061 date "2005-02-08" @default.
• W2102551061 modified "2023-10-16" @default.
• W2102551061 title "Supramolecular Control of Oligothienylenevinylene−Fullerene Interactions: Evidence for a Ground-State EDA Complex" @default.
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• W2102551061 doi "https://doi.org/10.1021/ol047527r" @default.
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