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• W2102582353 endingPage "16376" @default.
• W2102582353 startingPage "16366" @default.
• W2102582353 abstract "A new family of tetranuclear heterometallic assemblies, [Fe(III)2Gd2(H2L)4(η(2)-NO3)2]·2ClO4·2CH3OH·2H2O (1), [Fe(III)2Dy2(H2L)4(η(2)-NO3)2]·2ClO4·2CH3OH·2H2O (2), [Fe(III)2Tb2(H2L)4(η(2)-NO3)2]·2ClO4·2CH3OH·2H2O (3), have been synthesized employing a multi-dentate Schiff-base ligand, (E)-2,2'-(2-hydroxy-3-((2-hydroxyphenylimino)methyl)-5-methylbenzylazanediyl)-diethanol (H4L), Fe(ClO4)2·6H2O, and Ln(III) nitrate salts. These compounds have been structurally characterized by various analytical and spectroscopic techniques. The molecular structures of 1-3 have been confirmed by single crystal X-ray crystallography. All the three complexes contain two Fe(III) ions at the periphery and two Ln(III) ions in the centre. The entire assembly is held together by four doubly deprotonated [LH2](2-) ligands. All the three complexes (1-3) are dicationic in nature and possess an overall Z-type topology. Magnetic measurements reveal the presence of predominant ferromagnetic coupling for all the three compounds at low temperature. The presence of a frequency-dependent out-of-phase signal in the imaginary part of the ac susceptibility plot suggests a slow relaxation of magnetization for 3 (Fe(III)2Tb2). Furthermore, the magnetization dynamics of all the three complexes have been corroborated by Mössbauer spectroscopy." @default.
• W2102582353 created "2016-06-24" @default.
• W2102582353 creator A5008238569 @default.
• W2102582353 creator A5016616054 @default.
• W2102582353 creator A5016673925 @default.
• W2102582353 creator A5025514391 @default.
• W2102582353 creator A5041169537 @default.
• W2102582353 creator A5046011446 @default.
• W2102582353 date "2014-08-28" @default.
• W2102582353 modified "2023-10-13" @default.
• W2102582353 title "Synthesis, magnetism and Mössbauer studies of tetranuclear heterometallic {Fe^III₂Ln₂}(Ln = Gd, Dy, Tb) complexes: evidence of slow relaxation of magnetization in the terbium analogue" @default.
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• W2102582353 doi "https://doi.org/10.1039/c4dt01451k" @default.
• W2102582353 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25248081" @default.
• W2102582353 hasPublicationYear "2014" @default.
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