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• W2102586195 abstract "Abstract New Cu(II) complexes Cu(L′x)2, where L′x=L′1, L′2, L′3, L′4 are monoanion of unsubstituted, 5-Cl, 5-Br and 3,5-di-Br-substituted 2-hydroxybenzylamines of redox-active N-(3,5-di-tert-butyl-1-hydroxyphenyl)-2-hydroxybenzylamines were synthesized. Each compound of L′xH and Cu(L′x)2 as well as products of their oxidation and reduction by PbO2 and PPh3, respectively, was characterized by IR, UV-visible and ESR spectroscopy. ESR results showed that one-electron oxidation of mononuclear tetrahedrally distorted Cu(L′x)2 chelates with PbO2, via C-C coupling of the Cu(II)-stabilized ligand radical intermediates and by the oxidative dehydrogenation of amine-chelates, produce new Cu(II) complexes with square-planar geometry. The powder ESR spectra of these new Cu(II) complexes exhibit a triplet-state type pattern with the zero-field splitting due to interaction between the copper(II) pairs. Interaction of Cu(L′x)2 with PPh3 via intramolecular ligand-metal electron transfer results in the formation of radical species and reduction of the metal center. All radical intermediates were characterized by ESR parameters." @default.
• W2102586195 created "2016-06-24" @default.
• W2102586195 creator A5061116810 @default.
• W2102586195 date "2000-11-01" @default.
• W2102586195 modified "2023-09-27" @default.
• W2102586195 title "SYNTHESIS AND SPECTROSCOPIC STUDIES OF SOME NEW REDOX-ACTIVE BENZYLAMINE COMPLEXES OF COPPER(II) AND ESR STUDIES OF THEIR OXIDATIONREDUCTION PRODUCTS" @default.
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• W2102586195 doi "https://doi.org/10.1080/00958970008024563" @default.
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