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• W2102586578 abstract "Benzenesulfonyl cyanide and six para-substitution products were reduced electrochemically at a dropping mercury cathode, in DMF as solvent. A linear Hammett relation between the half-wave potentials of the first reduction wave and the σx-values was observed. This suggests the reduction mechanism being analogous for all molecules studied. The half-wave potentials could not be correlated with the electron affinities of these molecules, since for all compounds the first reduction wave is irreversible, due to the formation of mercurous intermediates. Performing electrochemical reduction within the ESR cavity spectra were obtained in some cases. For p-cyanobenzenesulfonyl and p-nitrobenzenesulfonyl cyanides these ESR spectra could be analysed and were assigned to the p-cyanobenzenesulfonyl and p-nitrobenzenesulfonyl dianion radicals, respectively. Prolonged reduction of p-nitrobenzenesulfonyl cyanide in DMF yields two additional ESR spectra, which could be assigned to the p-nitrobenzenesulfinyl and p-nitrobenzenesulfenyl dianions. So the SO2 group is reduced selectively in presence of the NO2 group." @default.
• W2102586578 created "2016-06-24" @default.
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• W2102586578 date "2010-09-02" @default.
• W2102586578 modified "2023-09-27" @default.
• W2102586578 title "Electrochemical reduction of arenesulfonyl cyanides" @default.
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• W2102586578 doi "https://doi.org/10.1002/recl.19740930104" @default.
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