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- W2102589911 abstract "Abstract Syntheses for the new bis(2,2,6,6‐tetramethylpiperidino)(phosphanyl)alumanes, tmp 2 AlP(SiMe 3 ) 2 , tmp 2 AlP(SnMe 3 ) 2 and (tmp 2 Al) 2 PPh are described along with spectroscopic characterization and X‐ray crystallographic structure determinations. In addition, the insertion reactions between tmp 2 AlP(SiMe 3 ) 2 and CO 2 , COS and CS 2 are described and compared with the outcomes for CO 2 insertion reactions with tmp 2 AlCl and tmp 2 AlMe. In the case of the amino‐phosphanyl‐alumane, the Al–P bond undergoes the insertion chemistry in contrast to Al–N bond insertions observed with tmp 2 AlCl and tmp 2 AlMe. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
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- W2102589911 date "2007-09-01" @default.
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- W2102589911 title "Synthesis and Reactivity of New Bis(tetramethylpiperidino)(phosphanyl)alumanes" @default.
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- W2102589911 doi "https://doi.org/10.1002/ejic.200700415" @default.
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